Then & Than usage

Hi there, may i know what is difference between Then & than and where we need to use that?

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THEN: It is an adverb. It means later, afterward.

I wake up at 6 am, and then take a shower.

It also means AT THAT SPECIFIC TIME.

He was the president then.

‘THAN’ AS A PREPOSITION: it is used for comparison for example 

My sister loves my mother more than me.

‘ THAN’ AS A SUBORDINATING CONJUNCTION:

Mangoes are sweeter than apples ( are).

He is taller than I (am).

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